To understand how a/c works will explain what is happening. A/c works by moving the haet from inside to outside. at the evaporator which is inside the car this action freezes the coils and the hot air of the inside condenses on the coils and water is drained outside. When there is no more water left in the air in side the car the windscreen goes clear. When you use the heater the water in the air in the car will still form as fog on the inside until the air temp dries it out. In short it is more efficient to use the a/c for short spells to clear the screen than the heater demister
SOURCE: air conditioner staying on...
Many cars use air conditioning as part of the defrost function. Cold air will clear windshield faster than hot air.
SOURCE: Front Defrost
clean the pollen filter wherever it is some are under the dash in the ac unit and some are below the grill vents where the wipers are.if this doesnt work then it could be a trampilla playing up thats controling the air in and recirculate .but if tis this then just disconnect the vacumn pipe and stick something in like a stic to hold the flap open .works on a vauxhaul zaffiro and a citreon zx
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