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Unfortunately, the RMT-D109A that comes with the DVP-S330 CD/DVD player (and possibly other models) will not control a Samsung TV with Smart functions. The RMT-D109A was probably programmed in 1999 (based on the copyright date of the manual). The first Smart TVs were not released until several years later. Universal remotes will only control devices that were released 6 months or more before the remote was programmed.
You would be better off purchasing a new universal remote to control both the Samsung TV and the CD/DVD Player (or other device) controlled by the RMT-D109A.
The TV code lists for the RMT-D109A are page 49 of the DVP -S330 manual. This manual is available on the product support page: https://esupport.sony.com/US/p/model-home.pl?mdl=DVPS330&template_id=1®ion_id=1&tab=manuals#/manualsTab . The direct link to the manual is currently https://docs.sony.com/release//DVPS330.PDF .
Programming procedure is too much to type in here by this window, and is not practical. If you wish to get details; check the site linked here. It have set-up code list & set-up procedure to many popular brand remote controls. See it in "Mosaic" view. It will make surf easier. http://electrohelponline.blogspot.com/
The Sony RMT-D187A cannot be programmed for a Dynex television. The brands supported according to Sony are: GoldStar, Hitachi, LG Mitsubushi / MGA, NEC, Panasonic, Philips, Pioneer, RCA, Samsung, Sharp, Sony, and Toshiba. Sorry, but it wont work on your TV.
Information found here: http://esupport.sony.com/US/perl/model-remote.pl?mdl=RMTD187A
How to Program the RMT-B107A Remote Control:
Follow these steps to program the remote control to operate a television.
1) Turn on the TV. 2) On the remote control, press and hold the TV I/O button. 3) While holding the TV I/O button, enter the manufacturer's code using the numeric buttons.
NOTE: If more than one code number is listed for the manufacturer, enter one code at a time until you find one that works.
4) Release the TV I/O button. 5) Point the remote control at the TV. 6) Press the TV I/O button to verify operation. NOTES:
If a new code number is entered, the code number previously entered will be erased. When the batteries are replaced, the programmed codes may be erased. It may be necessary to reprogram the remote after replacing the batteries. The operation of a combination deck of any kind is not guaranteed. Some product functions may not be able to be controlled by the remote control. Use the remote control provided with the component. In some rare cases, you may not be able to operate your non-Sony equipment with the supplied remote control. This is because your equipment may use a code that is not provided with this remote control. In this case, please use the equipment's own remote control. ************************************************************
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